INJECTION OF ADDITIVE TO SYNTHESIS PLANT OF HYDROCARBONS FROM SYNTHESIS GAS, ALLOWING TO CONTROL AND MAINTAIN UNIFORM CATALYST CONCENTRATION Russian patent published in 2018 - IPC C10G2/00 

Abstract RU 2647580 C2

FIELD: chemistry; technological processes.

SUBSTANCE: invention relates to process for synthesis of hydrocarbons from synthesis gas containing raw materials, in which solid Fischer-Tropsch catalyst is used in a three-phase reaction section, characterized in that said catalyst is maintained in suspension in the liquid phase by circulating the gas phase from the bottom upward in said reaction section. Wherein, in order to control and maintain a uniform concentration of catalyst particles in the reaction section, the following steps are carried out: (a) for any i that is in the range from 1 to n-1, where i is a natural integer from 1 to n-1, where n is the number of pressure measurement points along the longitudinal axis of the reactor and is at least 3, wherein measurement point 1 is the lowest point and measurement point n is the highest point in said reaction section, differential pressures are measured ΔPi between two consecutive pressure measurement points, spaced apart from each other by Δhi, and calculate the head loss per meter ΔGi=ΔPi/Δhi, (b) for each head loss per meter ΔGi in said catalyst suspension in the liquid phase, a value corresponding to the difference between two consecutive head loss per meter divided by their average value (ΔGi+1 – ΔGi)/((ΔGi+1 + ΔGi)/2 (c) if at least one of the values calculated in step (b) is greater than or equal to 5 %, inject at least one additive, containing at least one silicone polymer at least on the bottom of said reaction section.

EFFECT: use of invention allows to improve hydrodynamics of the gas/liquid/solid phase flow in the reaction section.

9 cl, 1 dwg, 1 ex, 2 tbl

Similar patents RU2647580C2

Title Year Author Number
FISHER-TROPSH SYNTHESIS 2015
  • Bouts Frederik Gideon
RU2670756C9
METHOD OF OBTAINING CATALYST OF HYDROCARBON SYNTHESIS AND ITS APPLICATION IN PROCESS OF HYDROCARBON SYNTHESIS 2009
  • Bota Jan Mateus
  • Ferrejra Al'Ta Karina
  • Rejnkhard Jan Petrus Karel
  • Velker-Niuvudt Kehtrin Aleksandra
RU2502559C2
METHOD AND DEVICE FOR FUNCTIONING OF BUBBLE REACTION COLUMN WITH THREE-PHASE REACTION METHOD FOR FISHER- TROPSCH SYNTHESIS 1997
  • Kazanav Dominik
  • Galt'E P'Er
  • Vil'Tar Zhan-Sharl'
RU2189857C2
METHOD FOR OPTIMISATION OF FUNCTIONING OF DEVICE FOR HYDROCARBON SYNTHESIS FROM SYNTHESIS-GAS BY CONTROL OF PARTIAL CO PRESSURE 2010
  • Mar'On Mari-Kler
  • Tasso Andrea
  • Kornaro Ugo
RU2525291C2
REACTION SYSTEM WITH BUBBLE COLUMN TYPE SUSPENDED LAYER FOR FISCHER-TROPSCH SYNTHESIS 2005
  • Onisi Jasukhiro
  • Fudzimoto Kenitiro
  • Ikhara Masaru
  • Suekhiro Esifumi
  • Morita Jasumasa
  • Inaba Kijosi
  • Simizu Tosio
  • Ivamoto Osamu
RU2384603C1
METHOD AND DEVICE FOR CARRYING OUT FISCHER-TROPSCH SYNTHESIS 2011
  • Shi Jujlin'
  • Vu Sjuchzan
  • Gon Lehj
  • Lin' Tsjuan'
  • Lv Jitszjun'
  • Bu Jifehn
  • Van Khunsjueh
RU2562770C2
FISCHER-TROPSCH SYNTHESIS PROMOTER CATALYST, METHOD OF PREPARING SAID CATALYST AND FISCHER-TROPSCH HYDROCARBON SYNTHESIS METHOD 2005
  • Riz Dehjvid Kristofer
RU2389548C2
PROCEDURE FOR CONVERSION OF SYNTHESIS GAS INTO HYDROCARBONS AT PRESENCE OF FOAMED SiC 2006
  • Fam-Khuu Kuong
  • Madani Beranzh
  • Ljakrua Maksim
  • Drehbin Lamia
  • Ledu Mark-Zhak
  • Savin-Ponse Sabin
  • Buske Zhak
  • Shvejkh Daniel'
RU2437918C2
METHOD FOR OBTAINING SYNTHETIC LIQUID HYDROCARBONS AND REACTOR FOR CARRYING OUT FISCHER-TROPSCH SYNTHESIS 2010
  • Ermolaev Vadim Sergeevich
  • Mordkovich Vladimir Zal'Manovich
  • Solomonik Igor' Grigor'Evich
  • Derevich Igor' Vladimirovich
  • Sineva Lilija Vadimovna
  • Mitberg Ehduard Borisovich
RU2440400C2
METHOD OF PRODUCING CATALYST FOR SYNTHESIS OF HYDROCARBONS AND USE THEREOF IN SYNTHESIS OF HYDROCARBONS 2008
  • Labushchan' Jokhan
RU2461422C2

RU 2 647 580 C2

Authors

Ero Zhan-Filipp

Forre Ann

Gazarian Zheremi

Maron Mari-Kler

Lekok Vensan

Bushe Sebasten

Della Torre Kyara

Minon Elza

Dates

2018-03-16Published

2013-12-04Filed