METHOD FOR PRODUCING COMPOUNDS, COMPOUNDS, COMPLEX METAL ORGANIC CATALYST Russian patent published in 2018 - IPC C07F9/54 C07F9/50 C07F15/00 

FIELD: chemistry.

SUBSTANCE: invention relates to the new compounds suitable for use in the chemical industry, of the formulas (I) - (IV)

; ; ; ,

where E is selected from -BR9R10, -CR11R12OH, -COR11; -SiR11R12R13; -SiR11R12-C₆H₄-PR7R8; R9 and R10 are halogen, hydroxyl, alkyloxy, aryloxy, cycloalkyloxy, alkyl, and cycloalkyl; R11, R12 and R13 represent a hydrogen atom, alkyl, cycloalkyl, and aryl; R1 and R2 represent alkyl, cycloalkyl, aryl, alkyloxy, cycloalkyloxy, aryloxy, alkylamino, cycloalkylamino, arylamino, metallocenyl groups; R3, R4, R5, R6 represent a hydrogen atom, alkyloxy, cycloalkyloxy, aryloxy, alkylamino, cycloalkylamino, and arylamino groups; wherein the alkyl group as such or as part of another substituent includes from 1 to 12 carbon atoms, the aryl group as such or as a part of another substituent contains from 5 to 20 atoms in the ring, the cycloalkoxy group as such or as a part of another substituent contains 3, 5, or 6 atoms in the ring; X represents F, Cl, Br, I; provided that, when X is Br, each of the groups R3, R4, R5, and R6 is hydrogen and R1 is Me or tert-Bu, then R2 is not tert-Bu or Me, respectively; X represents F, Cl, Br, I.

EFFECT: new compounds are proposed for use in catalytic hydrogenation or allylation, and effective methods for their production.

10 cl, 11 tbl, 76 ex