HIGH-CONCENTRATION SILVER SOLUTIONS FOR ETHYLENE OXIDE CATALYST PREPARATION Russian patent published in 2018 - IPC B01J23/50 B01J21/04 B01J23/04 B01J27/55 B01J37/02 B01J37/08 

Abstract RU 2674990 C1

FIELD: chemical or physical processes.

SUBSTANCE: invention relates to a silver catalyst for the synthesis of ethylene oxide. Described is a silver impregnation solution comprising: (i) silver ions, (ii) a silver concentration enhancer selected from at least one ammonium salt having an anionic component that is thermally decomposable; or at least one amino acid, or a combination thereof, (iii) at least one organic amine; and (iv) water; wherein said components (i)–(iii) are dissolved in said impregnation solution, and oxalic acid may or may not be included. Silver impregnation solution can contain significantly higher silver concentrations, including at least or above 33, 34, or 35 wt. %. Also described are methods for producing a silver catalyst by silver impregnation of a refractory support followed by calcination.

EFFECT: technical result is the creation of an impregnation solution, containing a silver salt in higher concentrations, maintaining stability during storage and use, that is ensuring complete dissolution of the silver compound in the absence of precipitation.

35 cl, 1 tbl, 8 ex

Similar patents RU2674990C1

Title Year Author Number
METHOD OF VAPOR-PHASE EPOXIDATION OF PROPYLENE INTO PROPYLENE OXIDE AND SILVER-CONTAINING CATALYST INVOLVED 1997
  • Pitchaj Rangasami
  • Kan Ehndrju
  • Gaffni Ehnn
RU2167872C2
CATALYST FOR AN OXIDATION OF ETHYLENE INTO ETHYLENEOXIDE 0
  • Enn Mari Lauritzen
SU1831369A3
METHOD OF PREPARING CATALYST FOR ALKYLENE OXIDE SYNTHESIS 1990
  • Ehrlind Magnus Torstejnson[Us]
  • Madan Mokhan Bkhasin[Us]
  • Seed Razi Seedmonir[Us]
RU2073564C1
ENHANCED CARRIERS FROM ALUMINIUM OXIDE AND SILVER-BASED CATALYSTS FOR PRODUCING ALKYLENE OXIDES 2004
  • Torstejnson Ehrlind M.
  • Bkhasin Madan Mokhan
  • Lju Al'Bert Chehn-Juj
  • Serafin Dzhuliana G.
  • Sejedmonir Sejed R.
  • Su Khvaili
RU2372342C2
METHOD OF PRODUCING OLEFIN OXIDE 2008
  • Gjukkel' Kristian J.
RU2476266C2
METHOD OF OBTAINING ALKYLENE OXIDE USING GAS-PHASE PROMOTER SYSTEM 2004
  • Chzhan Lipin
  • Su Khvaili
  • Serafin Dzhuliana G.
RU2360908C2
EPOXIDATION CATALYST AND METHOD OF PREPARATION THEREOF 1994
  • Uehjn Ehrrol Ehvans
RU2129465C1
CATALYSTS FOR OBTAINING ALKYLENE OXIDES, WHICH HAVE IMPROVED STABILITY, EFFICIENCY AND/OR ACTIVITY 2004
  • Serafin Dzhuliana G.
  • Lju Al'Bert Chehn-Juj
  • Sejedmonir Sejed R.
  • Su Khvaili
  • Shimanski Tomas
RU2360735C2
METHOD FOR PREPARATION OF SILVER-CONTAINING CATALYST FOR OXIDATION OF ETHYLENE INTO ETHYLENE OXIDE AND SILVER-CONTAINING CATALYST FOR OXIDATION OF ETHYLENE INTO ETHYLENE OXIDE 1987
  • Gosse Bokskhoorn[Nl]
RU2024301C1
MODIFIED CARRIERS FROM ALUMINIUM OXIDE AND CATALYSTS BASED ON SILVER FOR OBTAINING ALKYLENOXIDES 2004
  • Torstejnson Ehrlind M.
RU2340607C2

RU 2 674 990 C1

Authors

Tsao Lisin

Rokitskij Andzhej

Dates

2018-12-14Published

2014-12-18Filed