FIELD: technological processes.
SUBSTANCE: invention relates to production of heat-resistant materials and can be used for application of high-temperature antioxidative protective coatings on high-heat-resistant structural materials (carbon-carbon and carbon-ceramic composite materials, coal graphite materials, alloys based on Nb, Mo, W) widely used in aerospace, rocket and other industries. Proposed material for heat-resistant protective coating contains the following, wt%: titanium 35.0–40.0, molybdenum 8.0–10.0, boron 8.0–10.0, calcium 1.5–3.0, at least one element from the group of rare-earth metals (REM) 0.2–0.8, silicon – the rest. Material has a heterophase structure, mainly titanium diboride (TiB2), titanium and molybdenum disilicide of variable composition (TixMo1-xSi2, 0.1<x<0.87), disilicides of titanium, molybdenum and calcium (TiSi2, MoSi2, CaSi2) and silicon (Si) uncoupled into chemical compounds.
EFFECT: higher temperature and time intervals of serviceability of heat-resistant coatings in rate high-enthalpy streams of oxygen-containing gases at temperatures on surface Tw≥1,800 °C with simultaneous preservation of their catalytic activity at level Kw=2–5 m/s.
4 cl, 3 dwg, 2 tbl
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Authors
Dates
2019-04-23—Published
2017-12-05—Filed