CATALYST COMPONENT FOR POLYMERISATION OF PROPENE, METHOD FOR PRODUCTION THEREOF AND CATALYST CONTAINING THEREOF Russian patent published in 2019 - IPC C08F4/649 C08F4/654 C08F4/651 C08F10/06 

Abstract RU 2690192 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst component for polymerisation of propene, a method for production thereof, a catalyst for polymerisation of propene, a catalyst for prepolymerisation and a method of polymerising propene. Catalyst component contains titanium, magnesium, halogen and inner electron donor A, where said internal electron donor A is selected from compounds of formula I,

formula I,

where in IR formula is selected from hydrogen, hydroxy group and substituted or unsubstituted C1-C30-hydrocarbyl, preferably from hydrogen, hydroxy group and substituted or unsubstituted C1-C20-alkyl, C6-C30-aryl, C6-C30-heteroaryl, C7-C30-alkylaryl and C7-C30-arylkyl; R1 and R2 can be identical or different from each other and selected from hydrogen and substituted or unsubstituted C1-C30-hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20-alkyl, C6-C30-aryl, C7-C30-alkylaryl and C7-C30-arylkyl, where substituted C1-C30-hydrocarbyl means C1-C30-hydrocarbyl, substituted with a substituent selected from the group consisting of halogen, nitrogen atom, oxygen atom, hydroxy group, alkyl and alkoxy group. Catalyst component further comprises an internal electron donor B, which is at least one compound selected from a group comprising esters, compound ethers, ketones and amines, preferably from esters of polybasic carboxylic acids, esters of diols and diester. In the context of the present invention, a catalyst in which a compound of formula I is used, as an internal electron donor, when used for polymerisation propylene is characterized by high catalytic activity and slow reduction of activity.

EFFECT: obtained polymer has high melt index, wide molecular weight distribution (MWD) and high isotacticity.

17 cl, 6 tbl, 13 ex

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RU 2 690 192 C2

Authors

Van Tszun

Gao Minchzhi

Lyu Khajtao

Ma Tszin

Chen Tszyankhua

Kaj Syaosya

Ma Tszisin

Li Chansyu

Syuj Tszyantszun

Chzhan Syaofan

Li Syanchzhun

Chzhan Chzhisyuj

Duan Zhujlin

Yan Linna

Ma Chanyu

Dates

2019-05-31Published

2015-04-24Filed