FIELD: chemistry.
SUBSTANCE: catalyst component for olefin polymerization is disclosed. The catalyst component includes magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes a compound of imine with a ketone group as showed in the Formula I, where R is selected from a group consisting of C6-C30-aryl, 2,6-diisopropylphenyl, 2,6-dimethylphenyl, 2-hydroxypropylphenyl, 2,4,6-trimethylphenyl; R1 and R2 may be the same or different, each is independently selected from a group consisting of C1-C20-alkyl, phenyl, trifluoromethyl; A is (CR3R4)n, R3 and R4 may be the same or different, each is independently selected from a group consisting of hydrogen, C1-C20-alkyl, and n is equal to 0, 1, 2, 3, 4, 5 or 6. Catalyst for olefin polymerization containing a catalytic component, and the use of the catalytic component are additionally disclosed.
EFFECT: in the case of using catalyst in an olefin polymerization reaction, especially in a propene polymerization reaction, catalyst has high long-term activity and good response to hydrogen, and obtained polymer has characteristics of regulated isotactic index and relatively wide molecular-mass distribution.
Formula I
18 cl, 4 tbl, 94 ex
| Title | Year | Author | Number |
|---|---|---|---|
| CATALYST COMPONENT FOR OLEFIN POLYMERISATION AND CATALYST CONTAINING IT | 2015 |
|
RU2688689C2 |
| CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST AND THEIR APPLICATION | 2017 |
|
RU2757372C2 |
| CATALYST COMPONENT FOR POLYMERISATION OF PROPENE, METHOD FOR PRODUCTION THEREOF AND CATALYST CONTAINING THEREOF | 2015 |
|
RU2690192C2 |
| CATALYST COMPOSITION FOR OLEFIN POLYMERISATION AND USE THEREOF | 2014 |
|
RU2715995C2 |
| SOLID CATALYTIC COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST CONTAINING IT, AND USE THEREOF | 2003 |
|
RU2298014C2 |
| CATALYST COMPONENT FOR OLEFIN POLYMERISATION REACTION AND CATALYST COMPRISING SAID COMPONENT | 2011 |
|
RU2586114C2 |
| CATALYTIC COMPONENT FOR OLEFIN POLYMERIZATION, ITS PRODUCTION METHOD, AND CATALYST INCLUDING IT | 2019 |
|
RU2779192C2 |
| CATALYST COMPONENT, CATALYST, AND PRE-POLYMERIZATION CATALYST INTENDED FOR OLEFIN POLYMERIZATION, AND METHOD FOR OLEFIN POLYMERIZATION | 2018 |
|
RU2776708C2 |
| CATALYST COMPONENT FOR OLEFIN POLYMERISATION, PREPARATION METHOD THEREOF AND CATALYST COMPRISING SAME | 2014 |
|
RU2674026C2 |
| DEVICE FOR PRELIMINARY CONTACT OF CATALYST FOR CONTINUOUS POLYMERISATION OF OLEFINS AND METHOD OF PRELIMINARY CONTACT OF CATALYST | 2017 |
|
RU2738204C2 |
