POLYMETALLIC CATALYST DOPED WITH PHOSPHORUS AND LANTHANIDE Russian patent published in 2020 - IPC B01J27/185 B01J27/13 B01J23/63 B01J23/14 B01J37/02 B01J37/08 C10G35/09 

Abstract RU 2720998 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst, a method of producing a catalyst and use thereof in reforming. Reforming catalyst contains a substrate, at least one noble metal M, the content of which ranges from 0.02 to 2 wt % of catalyst weight, tin, phosphorus and cerium. Content of the element phosphorus ranges from 0.4 to 1 wt % of catalyst weight, and content of cerium ranges from 0.01 to 0.5 wt % of catalyst weight. Method of producing a reforming catalyst involves successive steps: a) preparing a substrate containing tin, phosphorus and a noble metal, b) drying the precursor obtained at step a) in a stream of neutral gas or in a gas stream containing oxygen at temperature below 200 °C and annealing at 350 to 650 °C, c) impregnation of dry calcined precursor obtained at step b), impregnating solution containing cerium precursor, d) drying the precursor obtained at step c) in a stream of neutral gas or in a stream of gas containing oxygen at temperature below 200 °C and annealing at temperature of 350–650 °C.

EFFECT: catalyst has improved selectivity and stability during reforming without deterioration of its activity.

12 cl, 1 tbl, 3 dwg, 10 ex

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RU 2 720 998 C2

Authors

Avenier, Priscilla

Diehl, Fabrice

Guegan, Carine

Sanchez, Eric

Dates

2020-05-15Published

2016-07-06Filed