FIELD: chemistry.
SUBSTANCE: invention relates to chemistry and can be used to produce a metastable compound with Bi2GeO5 crystal structure with the addition of silicon oxide (SiO2) without changing the crystal structure of the material. Method of producing germanate-silicate of bismuth involves preliminary mechanical mixing of initial powders: bismuth oxide Bi2O3 – 50 mol%, germanium oxide GeO2 – 10–49 mol% and silicon oxide SiO2 – 10–40 mol%, heating the obtained mixture in a platinum crucible to 1,100–1,200 °C is cured in this temperature range for 15–60 minutes, after which the obtained melt in the crucible is removed from the furnace and cooled in air.
EFFECT: laminar materials with a crystal structure of Auervillius are obtained, free from extraneous impurity phases.
1 cl, 10 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PRODUCTION OF BISMUTH GERMANATE-SILICATE WITH SILLENITE STRUCTURE | 2022 |
|
RU2788799C1 |
METHOD FOR PRODUCING BiGeO BISMUTH GERMANATE BY CASTING | 2020 |
|
RU2753671C1 |
METHOD OF PRODUCING BISMUTH GERMANATE BiGeO | 2017 |
|
RU2636090C1 |
METHOD FOR OBTAINING SELF-ADJUSTING CATALYST FOR OXIDATIVE DIMERIZATION OF METHANE IN BiO - SiO SYSTEM | 2020 |
|
RU2753653C1 |
METHOD FOR OBTAINING BiGeO COMPOUND | 2023 |
|
RU2810277C1 |
METHOD FOR OBTAINING BISMUTH SILICATE BiSiO | 2017 |
|
RU2654968C1 |
METHOD FOR PRODUCING BISMUTH GERMANATE BiGeO | 2018 |
|
RU2687924C1 |
METHOD FOR OBTAINING A BISMUTH GERMANATE BiGeO | 2017 |
|
RU2654946C1 |
METHOD OF PRODUCING CONTROLLED GLASS/δ*-BiO+BiSiO HETEROSTRUCTURE IN SYSTEM BiO-SiO (VERSIONS) | 2018 |
|
RU2691334C1 |
METHOD FOR PRODUCING BISMUTH GERMANATE BIGEO BY CASTING | 2021 |
|
RU2753672C1 |
Authors
Dates
2020-06-25—Published
2020-02-06—Filed