FIELD: electrical engineering.
SUBSTANCE: invention relates to electrical engineering and can be used in production of potassium-ion batteries and batteries based thereon. Disclosed is a cell of a potassium-ion battery, comprising a cathode made of a cathode composition containing a cyanocomplex of transition metals as an active cathode material, anode made from anode composition containing non-graphitized carbon as active anode material, and anhydrous organic electrolyte containing potassium hexafluorophosphate salt KPF6. Cyanocomplex of transition metals used is a compound of formula KxM1kM31-k[M2(CN)6]y·zH2O, where M1, M2 and M3 – transition metals, which can be identical or different, 0<x<4, 0≤k≤1, 0<y<2 and 0<z<20, preferably a connection is used KxMn[Fe(CN)6]y×zH2O. Cathode composition preferably includes KxM1kM31-k[M2(CN)6]y·zH2O in amount of 35–99 wt%, one or more electroconductive additives and one or more organic binding components. Anode composition includes non-graphitized carbon, one or more electroconductive additives and one or more organic binding components, wherein content of non-graphitized carbon is 35–99 wt%. Electrolyte used is a solution of a salt of KPF6 or a mixture of KPF6 with K[N(SO2F)2] and/or K[N(SO2CF3)2] with concentration of 0.1–8 M in a liquid organic solvent, preferably diethylene glycol dimethyl ether is used as a solvent.
EFFECT: higher stability of charge-discharge cycling characteristics is technical result of invention; with discharge capacity of 100 mA·h·g-1 with preservation of more than 89 %, up to 300 charge-discharge cycles are provided.
7 cl, 7 dwg, 1 tbl, 5 ex
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Authors
Dates
2020-07-29—Published
2019-12-09—Filed