FIELD: chemistry.
SUBSTANCE: present invention relates to a method for preparing bases of polyolefin anti-turbulent additives. This method is carried out by polymerization of alpha-olefins on a titanium-magnesium catalyst in a perfluorinated hydrocarbon medium. Reaction mixtures are used as alpha-olefins. The reaction mixtures were obtained by oligomerization of ethylene in a linear alpha-olefin medium using complexes of chromium (III) acetylacetonate and diphosphine ligands of the structure where X, X', X'', X'''are hydrogen atoms or methoxy substituents, R is a hydrogen atom or a trialkylsilyl substituent, R' is an alkyl substituent, Y is a structural fragment that forms a cycle with the participation of nitrogen and phosphorus atoms.
EFFECT: development of a process for obtaining finished dispersions of ultra-high molecular weight poly-alpha-olefins from available raw materials - ethylene - with the possibility of varying the type and ratio of comonomers, which are linear alpha-olefins and branched higher alpha-olefins, in order to obtain ready-made dispersions of low-temperature polyolefin ATAs.
1 cl, 2 tbl, 13 ex
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Authors
Dates
2021-06-18—Published
2020-09-24—Filed