FIELD: chemistry.
SUBSTANCE: invention relates to organic chemistry, specifically to a method of producing [1.1.1]propellan. Method involves reaction of 1,1-dibromo-2,2-bis(chloromethyl)cyclopropane with an effective amount of solid magnesium in anhydrous reaction conditions, selected to obtain [1.1.1]propellan.
EFFECT: providing a method of producing an end product in mild reaction conditions with providing commercially acceptable production efficiency.
21 cl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
CONTINUOUS FLOW METHODS OF OBTAINING BICYCLIC COMPOUNDS | 2018 |
|
RU2800934C2 |
SYNTHESIS OF MAGNOLOL AND ITS ANALOGUES | 2010 |
|
RU2510938C1 |
METHOD OF CONTINUOUS SYNTHESIS OF PHARMACEUTICAL INTERMEDIATE | 2019 |
|
RU2808483C2 |
AMINOEPOXIDE PREPARATION ACCOMPLISHED AS CONTINUOUS IN SITU SYNTHESIS | 1997 |
|
RU2194045C2 |
CROSS-COMBINATION METHODS | 2017 |
|
RU2777977C2 |
METHOD OF PRODUCING 1.1-DIBROMO-2.2-BIS-(CHLOROMETHYL) CYCLOPROPANE | 0 |
|
SU1509348A1 |
METHOD OF PREPARING 5-(1-(3,5-BIS(TRIFLUOROMETHYL)PHENOXY)ETHYL)CYCLOHEXANE-1,3-DIONE, ITS RACEMIC MIXTURE AND S-ENANTIOMER | 2023 |
|
RU2812607C1 |
SUBSTITUTED DIAMINO-CARBOXAMIDE AND DIAMINO-CARBONITRILE PYRIMIDINE DERIVATIVES, THEIR COMPOSITIONS AND METHODS OF TREATMENT USING THEM | 2012 |
|
RU2625309C2 |
SUBSTITUTED DIAMINOCARBOXAMIDE AND DIAMINOCARBONITRILE DERIVATIVES OF PYRIMIDINES, COMPOSITIONS THEREOF AND METHODS OF TREATING USE THEREOF | 2012 |
|
RU2697712C2 |
ELECTRON DONORS FOR PRODUCING ZIEGLER-NATTA PRECATALYST AND CATALYST SYSTEM FOR POLYMERISING OLEFINS | 2017 |
|
RU2736726C1 |
Authors
Dates
2024-06-04—Published
2020-08-12—Filed