FIELD: electrical engineering.
SUBSTANCE: invention relates to the field of electrical engineering, namely to an electrolyte and a supercapacitor with a double electric layer with such an electrolyte. Increased service life of organic ionic electrolyte in temperature range from minus 60 °C to plus 65 °C and a supercapacitor at negative temperatures is a technical result, which is achieved due to the fact that the electrolyte contains an ionic liquid and/or a quaternary alkyl ammonium salt with concentration of 0.1–1.4 mol/l, as well as a basic solvent acetonitrile (AN), a modifying additive with a volume fraction of 3–60%, and sodium or potassium benzoate in amount of 0.1–10 wt.%, wherein the quaternary alkylammonium salt is selected from the group containing triethylmethylammonium tetrafluoroborate (TEMA⋅BF4), tetraethylammonium tetrafluoroborate (TEA⋅BF4), 5-azonide spiro[4.4]nonane tetrafluoroborate (SBP⋅BF4), 1,1-dimethylpyrrolidinium tetrafluorbarate (DMP⋅BF4). Modifying additive used can be an organic carbonate or n-propyl acetate (n-PA) ester.
EFFECT: supercapacitor comprises a positive electrode with increased active mass relative to a negative one, which together with the proposed electrolyte formulation provides increased service life of the supercapacitor at negative temperatures.
8 cl, 3 dwg, 4 tbl
| Title | Year | Author | Number | 
|---|---|---|---|
| ELECTROLYTE, ELECTROLYTIC MIXTURE AND SOLUTION, CONDENSER, SECONDARY LITHIUM CELL AND METHOD OF OBTAINING QUATERNARY AMMONIUM SALT | 2004 | 
									
  | 
                RU2329257C2 | 
| SUPERCAPACITOR ELECTROLYTE | 2014 | 
									
  | 
                RU2552357C1 | 
| WORKING ELECTROLYTE FOR DOUBLE ELECTRIC LAYER CAPACITOR, METHOD OF ITS PREPARATION AND CAPACITOR WITH THIS ELECTROLYTE | 2015 | 
									 | 
                RU2612192C1 | 
| COMPOSITE SOLID ELECTROLYTE BASED ON IONIC ORGANIC SALTS OF SUBSTITUTED AMMONIUM WITH BUTYL AND METHYL RADICALS AND A HETEROGENEOUS ADDITION OF NANODIAMONDS | 2022 | 
									
  | 
                RU2796634C1 | 
| LITHIUM-ION BATTERY WITH OPERATING RANGE EXPANDED INTO LOW TEMPERATURE RANGE | 2017 | 
									
  | 
                RU2728531C2 | 
| ELECTROLYTE FOR DOUBLE-LAYER ELECTROCHEMICAL CAPACITOR | 2023 | 
									
  | 
                RU2807313C1 | 
| ELECTROLYTE FOR A DOUBLE-LAYER ELECTROCHEMICAL CAPACITOR AND METHOD FOR ITS PREPARATION | 2022 | 
									
  | 
                RU2782246C1 | 
| WORKING ELECTROLYTE FOR CONDENSER, METHOD OF ITS PREPARATION AND ALUMINUM ELECTROLYTIC CAPACITOR WITH SUCH ELECTROLYTE | 2019 | 
									
  | 
                RU2716491C1 | 
| METHOD FOR DETERMINING CONCENTRATIONS OF FLUORIDE IONS IN ELECTROLYTES | 2023 | 
									
  | 
                RU2812827C1 | 
| WORKING ELECTROLYTE FOR CONDENSER, METHOD OF ITS PREPARATION AND ALUMINUM ELECTROLYTIC CAPACITOR WITH SUCH ELECTROLYTE | 2019 | 
									
  | 
                RU2713639C1 | 
Authors
Dates
2024-10-03—Published
2022-12-06—Filed