FIELD: chemical technology, acetoxylation of conjugated dienes. SUBSTANCE: 1,3-cyclopentadiene is acetoxylated using acetic acid and air oxygen in the presence of intermetallic catalyst Rh2Te applied on the activated carbon at concentration 2.8-3.6 wt.-%, and carrier - the rest. Process is carried out at 80-85 C, under pressure 8.5-9.0 MPa with addition of sodium chloride to the raw at concentration 0.01-0.02% of catalyst mass. The yield is 94-96%. EFFECT: improved method of synthesis, increased yield of product. 4 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING OF A MIXTURE OF DIACETOXYCYCLOPENTENES | 1991 |
|
RU2026856C1 |
PROCESS FOR PREPARING CIS-3,5-DIACETOXYCYCLOPENTENE | 1991 |
|
RU2024490C1 |
CATALYST FOR 1,3-PENTADIENE ACETOXYLATION | 1991 |
|
SU1829186A1 |
1,3-BUTADIENE ACETOXYLATION CATALYST | 1988 |
|
SU1559495A1 |
1,3-BUTADIENE ACETOXYLATION CATALYST | 1988 |
|
SU1552433A1 |
CATALYST FOR AXIDATIVE DIACETOXYLATION OF 1,3-PENTADIENE | 1991 |
|
RU2024489C1 |
METHOD OF PRODUCING DIACETOXYBUTENES | 1988 |
|
SU1594927A1 |
3,4-DIACETOXYBUT-1-ENE ISOMERIZATION CATALYST | 1990 |
|
SU1820520A1 |
METHOD OF CYCLOPENTENE SYNTHESIS | 1992 |
|
RU2036890C1 |
METHOD FOR PRODUCING AND SEPARATING TRANS-SYN-TRANS- AND TRANS-ANTI-TRANS-ISOMERS OF DICYCLOHEXANO-18-CROWN-6 | 0 |
|
SU1270152A1 |
Authors
Dates
1996-05-10—Published
1991-02-15—Filed