FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of perfluoropolyoxaethylene dicarboxylic acid difluoroanhydrides of the general formula: FOC(CF2OCF2)nCOF wherein n = 1-10 in using tetrafluoroethylene oxide in the presence of catalyst in solvent at temperature (-15)-(-40)°C. In aim for simplifying the process tetrafluoroethylene oxide is added for interaction with fluorosulfonyloxydifluoroacetyl fluoride, and potassium fluoride or cesium fluoride is used a catalyst.
EFFECT: improved method of synthesis.
3 tbl, 2 ex
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SU740741A1 |
METHOD OF OBTAINING PERFLUORO-2,9-DIMETHYLDECANE-3,8-DION | 0 |
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Authors
Dates
2007-08-27—Published
1983-10-04—Filed