FIELD: manufacture of synthetic varnishes and enamels. SUBSTANCE: film-forming petroleum polymeric resin is prepared by copolymerization of unsaturated hydrocarbons containing C8-C9 fractions, C5 petroleum product pyrolysis fraction on the presence of catalyst system comprising TiCl4,, promoting additive and 2nd stage hydrocarbon solvent. Calculated amount of TiCl4 is fed to 1st stage, and monomer containing fractions and promoting additive (which includes mixture of lower carbonyl compound with water are fed in portions to both stages. TiCl4 to promoting additive weight ratio is maintained at 18-26: 1 at stage and 17-24:2 at 2nd stage, C5 fraction containing piperylene and tertamylenes being used in amount of 1.0-7.5% by weight of monomers at 1 st stage. Catalyst is deactivated with propylene oxide, and light carbohydrates are distilled. EFFECT: lower manufacturing cost and improved properties of coating. 1 dwg, 18 ex, 2 tbl
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Authors
Dates
1998-08-10—Published
1993-07-01—Filed