FIELD: chemistry of polymers, more particularly technology of preparing film-forming materials by block oligomerization or telomerization. SUBSTANCE: described is technology of preparing film-forming materials by block cooligomerization or telomerization of cooligomers of unsaturated C5-C10 hydrocarbons with propylene oxide in the presence of titanium tetrachloride complex with promoting mixture of lower carbonyl compound with water and copromoter. Copolymer is aliphatic C4-C6 alcohol or mixture thereof with C6-C54 ester. Amount of propylene oxide is 2.3-9.1 wt % per C5-C10 cooligomer. Amount of titanium tetrachloride catalyst complex with promoting mixture and copromoter is 4.6-12.4% based on cooligomer. EFFECT: more efficient preparation method. 3 tbl
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Authors
Dates
2001-01-10—Published
1999-03-01—Filed