FIELD: fine organic and organometal synthesis. SUBSTANCE: method comprises reacting alpha-olefins with ethyl aluminium dichloride and magnesium in the presence of two-component catalyst consisting of zirconacene dichloride and diisobutyl aluminium hydride in argon atmosphere under normal conditions for 8 h and subsequently adding boron trifluoride and stirring for 2-6 h. Solvent is tetrahydrofuran. Yield of desired products is 64-79%. EFFECT: new method of regio- and stereo-selective synthesis. 1 tbl
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Authors
Dates
1999-04-27—Published
1997-04-24—Filed