FIELD: polymerization catalysts. SUBSTANCE: invention relates to preparing butadiene polymerization catalyst that can find use in preparing catalysts for polymerization of dienes and olefins. Toluene solutions of cobalt compound and alkylaluminum chloride are added to toluene containing 0.010-0.035 wt % water and part of monomer thermostatically controlled at temperature from -30 to -25 C over the period of time from 10 min to 24 hr. Resulting solution is suitable for catalyzing 1,4-cys-polymerization of butadiene in aliphatic hydrocarbon (hexane, gasoline, etc.). EFFECT: enabled polymerization control with no need of additional reagents and allowed utilization of aliphatic hydrocarbon medium to carry out the process. 1 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING GEL-FREE LINEAR AND BRANCHED CIS-1,4- POLYBUTADIENE | 1996 |
|
RU2130036C1 |
METHOD OF PREPARING GEL-FREE 1,4-CIS-POLYBUTADIENE | 1998 |
|
RU2157818C2 |
METHOD OF PREPARING GEL-FREE CIS-1,4-POLYBUTADIENE | 1998 |
|
RU2154071C2 |
METHOD OF PREPARING CIS-1,4-POLYBUTADIENES | 1998 |
|
RU2157819C2 |
METHOD OF PRODUCING GEL-FREE cis-1,4-POLYBUTADIENE | 1993 |
|
RU2074198C1 |
METHOD OF PREPARING OF GELLESS CIS-1,4-POLYBUTADIENE | 1992 |
|
RU2011655C1 |
PROCESS FOR PREPARATION OF GEl-FREE CIS-1,4-POLYBUTADIENE MATERIAL | 1992 |
|
RU2005725C1 |
METHOD OF SYNTHESIS OF CIS-1,4-POLYBUTADIENE | 1996 |
|
RU2109758C1 |
PROCESS FOR PREPARING LOW-MOLECULAR WEIGHT POLYBUTADIENE | 1995 |
|
RU2082720C1 |
IMPACT-RESISTANT POLYSTYRENE MODIFIED WITH LINEAR AND BRANCHED DIENE RUBBERS | 2005 |
|
RU2291875C1 |
Authors
Dates
1999-09-20—Published
1998-04-13—Filed