FIELD: technology of high-molecular compounds, more particularly methods of preparation of stereoregular polydienes, using Ziegler-Natt catalyst systems, more particularly petrochemical industry. SUBSTANCE: described is method of preparing cis-1,4-polybutadiene by polymerization of butadiene is hedrocarbon solvent using catalyst system based on lantanoids and organoaluminium compounds: catalyst complex is formed and fed continuously to polymerization battery by mixing the components in pipeline. The claimed method makes if possible to prepare high-grade products and to regulate quality of polymer and polymerization process by varying ratios of catalyst components as process proceeds. EFFECT: more efficient preparation method. 7 ex, 1 tbl
Title | Year | Author | Number |
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METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1998 |
|
RU2139298C1 |
METHOD FOR PRODUCTION OF 1,4-CIS-POLYBUTADIENE | 1995 |
|
RU2099357C1 |
METHOD OF SYNTHESIS OF CIS-1,4-POLYBUTADIENE | 1996 |
|
RU2109759C1 |
METHOD FOR PRODUCTION OF CIS-1,4-DIENE RUBBER | 1995 |
|
RU2099359C1 |
METHOD FOR PREPARING CIS-1,4-DIENE RUBBER | 2003 |
|
RU2263121C2 |
METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1996 |
|
RU2096422C1 |
METHOD FOR PRODUCTION OF BUTADIENE RUBBERS | 1997 |
|
RU2196781C2 |
VULCANIZABLE CIS-1,4-BUTADIENE RUBBER BASED COMPOSITION | 1998 |
|
RU2154656C2 |
METHOD OF PREPARATION OF OIL-FILLED 1,4-CIS-POLYBUTADIENE | 1994 |
|
RU2091399C1 |
DIENE RUBBER PRODUCTION PROCESS | 1996 |
|
RU2109753C1 |
Authors
Dates
2000-06-27—Published
1998-07-06—Filed