FIELD: sludge recovery from surface depositions of chemical equipment.
SUBSTANCE: invention relates to method for recovery of sludge containing platinum-group metals from equipment using platinum metal-based catalysts. Method includes treatment with aqueous solution of active chemical agent (e.g. sodium-ammonium-substituted ethylenediaminetetraacetic salts) while controlling pH value and removing sludge retained on treated surface with diluted aqueous solution of mineral salts or mixture thereof. pH value is adjusted at 2-10, preferably at 3-9 by adding of organic acid selected from group containing citric, oxalic, maleic, phthalic, adipic, glutaric, succinic acids or basic agents selected from sodium hydroxide, potassium hydroxide, sodium carbonate or potassium carbonate, and hydrochloric acid, sulfuric acid or phosphoric acid is used as mineral acid.
EFFECT: recovery platinum-group metal with improved yield.
4 cl, 1 tbl, 12 ex
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Authors
Dates
2005-01-27—Published
2003-06-03—Filed