FIELD: detoxification methods.
SUBSTANCE: invention relates to detoxifying polychlorinated organic wastes containing toxic high-boiling substances. For this aim, wastes are hydrogenised on supported palladium catalyst at 60-130°C and pressure 10-50 atm in presence of 10-20% sodium hydroxide solution in biphasic water/hydrocarbon system. According to invention, hydrocarbon solution of waste, prior to be subjected to hydrogenation, is filtered at 70-100°C through filter of nonwoven polymeric material allowing waste particles at least 1 μm in size to be retained, after which reaction mixture is charged with lower aliphatic alcohol in amount 1 to 20 wt %.
EFFECT: essentially increased waste processing productivity with minimum formation of secondary toxic substances.
5 cl, 1 tbl, 12 ex
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Authors
Dates
2005-07-10—Published
2004-03-30—Filed