FIELD: rubber industry.
SUBSTANCE: process consists in copolymerization of isobutylene with isoprene in organic solvent in presence of catalyst: water-protonated ethylaluminum sesquichloride with summary content of protonated complexes 5 to 45% and ratio of protonated complex based on ethylaluminum dichloride to protonated complex based on diethylaluminum chloride between 0.01:1 and 0.5:1. Organic solvent is a mixture of ethyl chloride and isopentane taken is such proportions that content of the former in total blend attains 23.5 to 40 wt % and resulting butyl rubber does not loose its solubility in medium wherein it is formed. In such case, butyl rubber solution has lowered viscosity so that more complete conversion of monomers in polymerization process is allowed.
EFFECT: increased content of solids in polymerizate and thereby increased productivity of rubber manufacturing process.
2 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING BUTYL RUBBER | 1999 |
|
RU2177009C2 |
BUTYL RUBBER PRODUCTION PROCESS | 2004 |
|
RU2270839C1 |
METHOD FOR PRODUCTION OF BUTYL RUBBER | 1978 |
|
SU792901A1 |
BUTYL RUBBER PRODUCTION PROCESS | 2001 |
|
RU2184745C1 |
PROCESS FOR PREPARING BUTYL RUBBER | 1994 |
|
RU2071481C1 |
METHOD OF PRODUCING BUTYL RUBBER | 1994 |
|
RU2092498C1 |
METHOD OF PREPARING BUTYL RUBBER | 1994 |
|
RU2096423C1 |
BUTYL RUBBER PRODUCTION PROCESS | 1999 |
|
RU2155195C1 |
HALOGENATED BUTYL RUBBER PRODUCTION PROCESS | 2000 |
|
RU2169737C1 |
BUTYL RUBBER PRODUCTION PROCESS | 2002 |
|
RU2238953C2 |
Authors
Dates
2005-08-27—Published
2004-04-29—Filed