FIELD: production of high temperature superconductors.
SUBSTANCE: invention relates to electrochemical synthesis of metal β-diketonates, in particular acetylacetonates. Synthesis of Cu(II) and Zn(II) acetylacetonates in carried out by electrolysis of acetylacetone solution and base electrolyte in acetonitryl in ratio of (1:10):0.5:100, with electrodes made of metal presenting in produced acetylacetonate, at current density not more mA/cm2 by using pulse current. Pulse time is controlled by pulse forming unit connected in parallel to elecrtolyzer. As base electrolyte preferably lithium perchlorate or lithium chloride is used.
EFFECT: controlled process for production of metal acetylacetonates.
5 cl, 2 ex, 1 dwg
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PREPARING DISSIMILAR-LIGAND COMPLEXES OF RARE-EARTH ELEMENTS WITH ACETYLACETONE AND CIS- OR TRANS-BUTEDIOIC ACID | 2002 |
|
RU2237749C2 |
| METHOD OF PREPARING RARE-EARTH ELEMENT ACETYLACETONATES | 2001 |
|
RU2191190C1 |
| METHOD OF PRODUCING BETA-DIKETONATE OF PALLADIUM (AND) OR COPPER (II) | 2010 |
|
RU2433114C1 |
| PLATINUM(II) BETA-DIKETONATES OBTAINING METHOD | 2017 |
|
RU2659073C1 |
| METHOD FOR PRODUCING POROUS MICROFIBRES OF COPPER(II) OXIDE | 2023 |
|
RU2813055C1 |
| METHOD FOR PRODUCING COPPER(II) OXIDE NANOPARTICLES | 2020 |
|
RU2747435C1 |
| METHOD OF PRODUCING COORDINATION COMPOUNDS OF COPPER (II) WITH 5,5-DIMETHYL-1,3-CYCLOHEXANEDIONE | 2012 |
|
RU2493161C1 |
| HETEROMETALLIC NEODYMIUM (III) AND IRON (III) MALATE AND A METHOD FOR PREPARATION THEREOF | 2003 |
|
RU2255082C2 |
| METHOD FOR OBTAINING COORDINATION COMPOUND OF COPPER(II) WITH PICOLINIC ACID | 2017 |
|
RU2654464C1 |
| METHOD OF PRODUCING HETEROMETAL Fe (III) AND Nd (III) MALATE | 2007 |
|
RU2351602C1 |
