FIELD: industrial organic synthesis.
SUBSTANCE: before olefin-containing raw material is brought into contact with isomerization catalyst, one or several components of the raw material are subjected to preliminary treatment coming into contact with preliminary treatment material containing zeolite with pore size at least 0.35 nm. Initial olefin is, in particular, vinylidene olefin of general formula CH2=C(R1)R2, wherein R1 and R2 independently represent alkyl groups having at least 2 carbon atoms so that molecular structure includes at least one allyl hydrogen atom.
EFFECT: increased selectivity.
10 cl, 1 tbl, 11 ex
| Title | Year | Author | Number |
|---|---|---|---|
| VINYLIDENE OLEFIN ISOMERIZATION PROCESS | 2002 |
|
RU2283825C2 |
| MODIFIED ZEOLITES AND MOLECULAR SIEVES | 2001 |
|
RU2278818C2 |
| ALKYLATION FOR OBTAINING DETERGENTS WITH APPLICATION OF CATALYST SUBJECTED TO EXCHANGE WITH RARE EARTH ELEMENT | 2010 |
|
RU2510639C2 |
| METHOD OF ISOMERIZATION OF LINEAR OLEFINS INTO BRANCHED OLEFINS, AND CATALYTIC COMPOSITION | 1994 |
|
RU2140410C1 |
| BRANCHED PRIMARY ALCOHOL AND ITS DERIVATIVES | 2001 |
|
RU2281279C2 |
| METHOD OF PRODUCING ALKYLBENZENES ON SOLID ACID CATALYST | 2007 |
|
RU2447051C2 |
| METHOD OF ISOMERIZING CARBON OLEFIN FRAMEWORK (VERSIONS) | 1998 |
|
RU2186756C2 |
| METHOD FOR PREPARING ALKYLARYLSULFONATES | 2001 |
|
RU2312099C2 |
| METHODS USING SSZ-95 MOLECULAR SIEVE | 2015 |
|
RU2784871C2 |
| METHODS OF ISOMERISATION OF PARAFFINS HAVING 5 AND 6 CARBON ATOMS, WITH NETHYLCYCLOPENTANE ISOLATION AND DEVICE FOR ITS REALISATION | 2006 |
|
RU2364583C2 |
