ALKYLATION CATALYST PREPARATION METHOD Russian patent published in 2006 - IPC B01J37/30 B01J29/40 C07C15/73 

Abstract RU 2289477 C1

FIELD: organic synthesis catalysts.

SUBSTANCE: invention relates to petrochemical processes, in particular production of ethylbenzene via alkylation of benzene with ethylene catalyzed by solid acid catalyst, and provides elevated-strength (cleavage strength above 2 kg/mm diameter) catalyst showing high characteristics regarding activity (theoretical yield of ethylbenzene 65.83-70.7%) and selectivity (yield of ethylbenzene based on converted benzene 68,18-71.4%). This is achieved by way of mixing Pentasil-type zeolite with binder, said zeolite having been preliminarily subjected to exchange of cations: consecutively ammonium and calcium or magnesium. As binder, pseudoboehemite-structure aluminum hydroxide, to which inorganic acid was add to pH 2-4, is utilized. Molding mass is characterized by calcination loss 35-45 wt %. Heat treatment is effected in one to three steps.

EFFECT: improved strength, activity and selectivity of catalyst.

2 tbl, 5 ex

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RU 2 289 477 C1

Authors

Rakhimov Khalil Khaljafovich

Ishmijarov Marat Khafizovich

Smirnov Vladimir Konstantinovich

Irisova Kapitolina Nikolaevna

Rogov Maksim Nikolaevich

Prokopenko Aleksej Vladimirovich

Mjachin Sergej Ivanovich

Talisman Elena Nikolaevna

Ponjatkova Zoja Jur'Evna

Chvanova Ekaterina Sergeevna

Dates

2006-12-20Published

2005-11-15Filed