FIELD: organic chemistry.
SUBSTANCE: claimed method includes reaction of C60-fullerene with 1,2-diaminepropane in presence of Cp2TiCl2 as catalyst in toluene medium at room temperature (approximately 20°C) for 44-52 hours. Yield of target product is 73-90 %. Compound of present invention is useful as chelating agent, sorbent, biologically active compound and for production of new materials with desired electronic, magnetic and optical properties. .
EFFECT: new compound; method of increased yield and selectivity.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
METHOD FOR PREPARING 1-{[1-(HYDROXYMETHYL)PROPYL]AMINO}-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309938C1 |
METHOD OF 2,3-FULLERO[60]-7-PHENYL-7-PHOSPHABICYCLO[2,2,1]HEPTANE PRODUCTION | 2007 |
|
RU2350619C1 |
METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
METHOD FOR PREPARING 1-(N,N-DICYCLOHEXYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310645C1 |
METHOD OF PRODUCING 1-(2-PROPENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
|
RU2372334C2 |
METHOD FOR PREPARING 1-(6,7-DIMETHOXY-1,2,3,4-TETRAHYDROISOQUINOLINE-2-YLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309954C1 |
Authors
Dates
2007-10-10—Published
2006-05-05—Filed