FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing new 1-(2-propenyl)-2,5-dimethyl-3,4-fullero[60]pyrrolidine with general formula (1)
, which involves reacting fullerene[60] with diethylallylamine in molar ratio C60: diethylallylamine equal to 0.01:(0.01-0.011), in the presence of a Cp2TiCl2 catalyst in amount of 15 to 25 mol % with respect to fullerene[60], in toluene medium as solvent at temperature ranging from 140 to 160°C for 2 to 4 hours.
EFFECT: compound can be used as a complexing agent, sorbent, biologically active compound, as well as when producing new materials with given electronic, magnetic and optical properties.
2 dwg, 1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-(2,7-OCTADIENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
|
RU2315038C1 |
| METHOD FOR PREPARING 1-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL))-1H-1,2,4-TRIAZOLE | 2005 |
|
RU2283310C1 |
| METHOD FOR PREPARING 2-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL)PHENOL | 2005 |
|
RU2283302C1 |
| METHOD FOR PRODUCTION OF N,N,1-TRIMETHYL-2-(3,4-FULLERO[60])PYRROLIDINE AMINE | 2005 |
|
RU2283834C1 |
| METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
| METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PRODUCTION OF 5-METHYL-2,3-FULLERO[60]PIPERAZINE | 2006 |
|
RU2307832C1 |
| METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
