FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of 1-(N,N-dicyclohexylamino)-1,2-dihydro[60]fullerene of the general formula (1): 
. Method involves interaction of fullerene-C60 with N,N-dicyclohexylamine in the mole ratio fullerene-C60 : N,N-dicyclohexylamine = 0.01:(0.01-0.011) in the presence of zirconacene dichloride (Cp2ZrCl2) as a catalyst taken in the amount 15-25 mole% with respect to fullerene-C60, in toluene medium as a solvent, at room temperature (˜20oC) for 42-54 h. The yield of the end product is 69-92%. Synthesized compound can be used as chelating agents, sorbents, biologically active compounds, and in creature of novel materials with desired electronic, magnetic and optical properties.
EFFECT: improved method of synthesis.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PREPARING 1-(N-PHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310646C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
| METHOD FOR PRODUCTION OF N,N,1-TRIMETHYL-2-(3,4-FULLERO[60])PYRROLIDINE AMINE | 2005 |
|
RU2283834C1 |
| METHOD FOR PREPARING 1-{[1-(HYDROXYMETHYL)PROPYL]AMINO}-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309938C1 |
| METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
| METHOD OF PRODUCING 1-ALKOXY- OR 1-CYCLOALKOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2384561C2 |
| METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
| METHOD OF PREPARING 1-[3-HYDROXY-3-ARYLPROP-1-YL]-1,2-DIHYDRO[60]FULLERENES | 2005 |
|
RU2290367C1 |
| METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
