FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of 1-(N-phenylamino)-1,2-dihydro[60]fullerene of the formula 1 
. Method involves interaction of fullerene-C60 with aniline in the mole ratio fullerene-C60 : aniline = 0.01:(0.01-0.011) in the presence of hafnocene dichloride (Cp2HfCl2) as a catalyst taken in the amount 15-25 mole% with respect to fullerene-C60, in toluene medium as a solvent, at temperature 140-160oC for 4-8 h. The yield of the end product is 68-95%. Synthesized compound can be used as chelating agents, sorbents, biologically active compounds, and in creature of novel materials with desired electronic, magnetic and optical properties.
EFFECT: improved method of synthesis.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-(6,7-DIMETHOXY-1,2,3,4-TETRAHYDROISOQUINOLINE-2-YLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309954C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
| METHOD FOR PREPARING 1-(N,N-DICYCLOHEXYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2310645C1 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PREPARING 1-{[1-(HYDROXYMETHYL)PROPYL]AMINO}-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309938C1 |
| METHOD FOR PREPARING 1-(4-QUINOLINAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2313521C1 |
| METHOD OF PRODUCING 1-PHENOXY-1,2-DIHYDRO[60]FULLERENE | 2008 |
|
RU2385859C2 |
| METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
| METHOD OF PRODUCING 1-(2-PROPENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
|
RU2372334C2 |
| METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
