FIELD: organic chemistry.
SUBSTANCE: invention relates to method for production of N,N,1-trimethyl-2-(3,4-fullero[60])pyrrolidine amine of formula 1 
.
Claimed method includes reaction of fullerene[60] (C60) with N,N,N,N-tetramethylmethane diamine of general formula (CH3)2-N-CH2-N-(CH3)2 in C60:(CH3)2-N-CH2-N-(CH3)2 molar ratio of 0.01:(0.01-0.011) in presence of Cp2TiCl2 as catalyst in amount of 15-25 mol.% based on fullerene in argon atmosphere in toluene medium as solvent at 140-160°C for 2-4 hours. Yield of target product is 79-89 %.
EFFECT: compound useful as complexing agents, sorbents, biologically active materials and in production of materials with desired electronic, magnetic and optical characteristics.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PREPARING 1-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL))-1H-1,2,4-TRIAZOLE | 2005 |
|
RU2283310C1 |
| METHOD FOR PREPARING 2-(1-METHYL-2-(3,4-FULLERO[60]-PYRROLIDINYL)PHENOL | 2005 |
|
RU2283302C1 |
| METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309939C1 |
| METHOD FOR PREPARING 1-[1-(METHYL-2-(3,4-FULLEROPYRROLIDINYL)]-1H-1,2,3-BENZOTRIAZOLE | 2005 |
|
RU2291153C1 |
| METHOD FOR PREPARING 1-(N,N-DIPHENYLAMINO)-1,2-DIHYDRO[60]FULLERENE | 2006 |
|
RU2309941C1 |
| METHOD FOR PREPARING 1-PHENYL-2,5-DIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2310660C1 |
| METHOD OF PRODUCING 1-(2-PROPENYL)-2,5-DIMETHYL-3,4-FULLERO[60]PYRROLIDINE | 2006 |
|
RU2372334C2 |
| METHOD FOR PREPARING 1,2,5-TRIALKYL-3,4-FULLERO[60]PHOSPHOLANES | 2006 |
|
RU2315055C1 |
| METHOD OF 2,3-FULLERO[60]-7-PHENYL-7-PHOSPHABICYCLO[2,2,1]HEPTANE PRODUCTION | 2007 |
|
RU2350619C1 |
| METHOD FOR PREPARING 8-ETHYL-6,7-FULLERO[60]-3-OXA-8-AZABICYCLO[3.2.1]OCTANE | 2006 |
|
RU2315047C1 |
