FIELD: chemistry of metalloorganic compounds, catalysts.
SUBSTANCE: invention relates to a metalloorganic compound and catalytic composition comprising indicated metalloorganic compound of the general formula (I): [HC(CRR'R'')(CRR'R'')]+[M2X9]- wherein R means hydrogen atom (H) or M1R1R2R3; R' means M1R4R5R6; R'' means H, (C1-C12)-alkyl; M means Zr or Hf; M' means Si or Sn; X means halogen atom; R1-R6 mean (C1-C12)-alkyl. Also, invention relates to a method for homo- and co-polymerization of isoolefins or olefins in the presence of indicated metalloorganic compound. Described catalytic system based on compound of the formula (I) shows high activity in the co-polymerization reaction of isobutylene.
EFFECT: valuable chemical and catalytic properties of compound.
10 cl, 2 tbl, 14 ex
Title | Year | Author | Number |
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Authors
Dates
2008-02-10—Published
2003-01-21—Filed