METHOD FOR EPOXIDATION OF OLEFINS Russian patent published in 2008 - IPC C07D301/12 C07D303/04 

Abstract RU 2320650 C2

FIELD: chemical technology.

SUBSTANCE: invention relates to a method for continuous epoxidation of olefins with hydrogen peroxide in the presence of a heterogeneous catalyst accelerating the epoxidation reaction. Aqueous reaction mixture comprises the following components: (1) olefin; (2) hydrogen peroxide; (3) less 100 ppm of alkaline metals, alkaline-earth metals in ionogenic, complex or covalently bound form, as bases or base cations possessing pH value pkB less 4.5, or their combination, and at least 100 ppm of bases or base cations possessing pH value pkB at least 4.5, or their combination. Values in ppm are given as measure for the total mass of hydrogen peroxide in the reaction mixture.

EFFECT: improved method of reaction.

20 cl, 2 tbl, 14 ex

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Authors

Brasse Klaudia

Khas Tomas

Khofen Villi

Shtokhniol' Guido

Tile Georg

Vell' Vol'Fgang

Dates

2008-03-27Published

2003-09-23Filed