FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for catalytic epoxidation of (C2-C6)-olefins with hydrogen peroxide. Method is carried out in the flow-type reaction system of continuous effect wherein the reaction mixture is passed through a immobile catalytic layer inside of reactor fitted with a cooling device and in simultaneous maintaining the temperature profile into the reactor wherein the cooling medium temperature in the cooling agent is at least 40°C and the maximal temperature inside of the catalytic layer is 60°C, not above. Invention provides improving the conversion degree and selectivity of the product by using the conventional systems.
EFFECT: improved method of synthesis.
12 cl, 1 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR EPOXIDATION OF OLEFINS | 2002 |
|
RU2291152C2 |
METHOD FOR CATALYTIC EPOXIDATION OF PROPENE | 2002 |
|
RU2303035C2 |
METHOD FOR EPOXIDATION OF OLEFINS | 2003 |
|
RU2320650C2 |
METHOD OF EPOXIDATION OF OLEFINS | 2003 |
|
RU2327694C2 |
OLEFIN EPOXIDATION PROCESS | 2003 |
|
RU2322442C2 |
METHOD OF PROPANE EPOXIDATION | 2004 |
|
RU2340608C2 |
METHOD OF PURIFYING CRUDE PROPENE-OXIDE | 2003 |
|
RU2330032C2 |
METHOD OF PRODUCING OLEFIN OXIDE | 2008 |
|
RU2480459C2 |
METHOD OF OBTAINING ALKYLENEOXIDE | 2004 |
|
RU2333206C2 |
METHOD FOR EPOXIDATION OF OLEFIN | 2015 |
|
RU2656608C1 |
Authors
Dates
2006-12-27—Published
2002-03-02—Filed