FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for the catalytic epoxidation reaction of (C2-C6)-olefins with hydrogen peroxide in the flow-type continuous reaction system. The reaction mixture is passed through an immobile catalytic layer with the re-flowing regimen process with at least partial removal of reaction heat formed during the reaction. The process can be carried out in the multiple reaction mixture comprising an aqueous liquid phase enriched with hydrogen peroxide containing methanol and a liquid organic phase enriched with propane. Methanol can be used as an organic solvent. Invention provides improves the conversion degree and selectivity with respect to the end product.
EFFECT: improved method of synthesis.
16 cl, 1 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR CATALYTIC EPOXIDATION OF PROPENE | 2002 |
|
RU2303035C2 |
METHOD FOR EPOXIDATION OF OLEFINS | 2002 |
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METHOD OF PRODUCING PROPYLENE OXIDE | 2010 |
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RU2528385C2 |
METHOD OF REGENERATING CATALYST BASED ON TITANIUM-CONTAINING ZEOLITE FOR EPOXIDATION OF PROPYLENE | 2016 |
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RU2702349C2 |
METHOD OF PROPANE EPOXIDATION | 2004 |
|
RU2340608C2 |
Authors
Dates
2007-01-10—Published
2002-03-04—Filed