FIELD: chemistry.
SUBSTANCE: described is catalyst of purification of hydrogen-containing gas mixture from CO, including metal copper and/or copper oxide and cerium dioxide, applied on carbon carrier, as such mezoporous graphite-like carbon material is used, which represents three-dimensional matrix with pore volume 0.2-1.7 cm3/g, formed with ribbon carbon layers 100-10000 A thick and curvature radius 100-10000 A, having true density equal 1.80-2.10 g/cm3, X-ray density 2.112-2.236 g/cm3, porous structure with pore distribution with additional maximum within the range 200-2000 A or biporous structure with pore distribution with additional maximum within the range 40-200 A and specific surface 50-500 m2/g, catalyst having the following composition, wt %: Cu - 5.0-10.0; Ce - 15.0-20.0; O - 4.8-7.2; C - 75.2-62.8. Also described is method of catalyst preparation by subsequent or simultaneous impregnation of said carrier with cerium and copper solutions.
EFFECT: high efficiency, selectivity and enhanced mechanical strength of catalyst.
2 cl, 1 tbl, 6 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| CATALYST, METHOD OF PREPARATION THEREOF, AND METHOD FOR TREATMENT OF HYDROGEN- RICH GAS MIXTURES TO REMOVE CARBON MONOXIDE | 2001 | 
 | RU2191070C1 | 
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| CATALYST, PREPARATION METHOD THEREOF AND AMMONIA OXIDATION METHOD | 2010 | 
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| CATALYST, PREPARATION METHOD THEREOF AND METHOD OF PRODUCING HYDROGEN | 2010 | 
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| CATALYST, PREPARATION METHOD THEREOF AND METHOD OF DECOMPOSING NITROGEN OXIDE | 2010 | 
 | RU2430781C1 | 
| CATALYST, METHOD OF MAKING IT (VERSIONS) AND METHOD OF HYDRODEOXYGENATION OF FATTY ACIDS, THEIR ESTERS AND TRIGLYCERIDES | 2007 | 
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| CATALYST AND METHOD FOR OBTAINING GAS MIXTURE ENRICHED BY HYDROGEN FROM DIMETHYL ETHER AND AIR | 2017 | 
 | RU2677875C1 | 
| METHOD OF PREPARATION OF Pd-CeO APPLIED CATALYSTS | 2005 | 
 | RU2297279C1 | 
| METHOD OF HYDROGENOUS GAS MIXTURE CLEANING FROM CARBON OXIDE (VERSIONS) | 2006 | 
 | RU2359741C2 | 
Authors
Dates
2008-10-27—Published
2007-06-04—Filed