METHOD OF PRODUCING SULFOXIDES BY CATALYTIC OXIDATION OF THIOESTERS Russian patent published in 2009 - IPC C07C315/02 C07C317/14 

Abstract RU 2349583 C1

FIELD: chemistry.

SUBSTANCE: present invention pertains to the method of producing sulfoxides through oxidation of thioesters using hydrogen peroxide, in the presence of a catalyst in the form of a zinc salt, for example Zn(NO3)2·6H2O, or a zinc coordination compound, for example a homochiral microporous coordination polymer with the formula: [Zn2BDC·(L-Lac)·DMF]·(DMF)x, where BDC - terephthalic acid dianion, L-Lac - lactic acid dianion, DMF - dimethyl formamide.

EFFECT: method allows for obtaining sulfoxides with high conversion and selectiveness of the process.

3 cl, 2 tbl, 2 ex

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RU 2 349 583 C1

Authors

Nuzhdin Aleksej Leonidovich

Dybtsev Danil Nikolaevich

Bryljakov Konstantin Petrovich

Fedin Vladimir Petrovich

Talzi Evgenij Pavlovich

Dates

2009-03-20Published

2007-06-20Filed