FIELD: chemistry.
SUBSTANCE: present invention pertains to the method of producing sulfoxides through oxidation of thioesters using hydrogen peroxide, in the presence of a catalyst in the form of a zinc salt, for example Zn(NO3)2·6H2O, or a zinc coordination compound, for example a homochiral microporous coordination polymer with the formula: [Zn2BDC·(L-Lac)·DMF]·(DMF)x, where BDC - terephthalic acid dianion, L-Lac - lactic acid dianion, DMF - dimethyl formamide.
EFFECT: method allows for obtaining sulfoxides with high conversion and selectiveness of the process.
3 cl, 2 tbl, 2 ex
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Authors
Dates
2009-03-20—Published
2007-06-20—Filed