FIELD: sewage treatment facilities.
SUBSTANCE: invention may be used in production of fluoroberyllate ammonia - initial product for production of beryllium and its compounds. Method for processing of beryllium metal wastes includes operations of flushing from foreign admixtures, chopping to size of 2-5 mm and dilution in solution of ammonia bifluoride during heating. Process of beryllium metal wastes dilution is done in presence of oxidant - nitric acid or ammonia nitrate taken in amount of 0.4-0.8 mole per mole of metal powder, at the temperature of 85-90°C. Ammonia bifluoride is taken in amount of 180-200% from stoichiometry.
EFFECT: invention makes it possible to reduce release of fire-and-explosive hazardous gaseous hydrogen and to prevent possible exhaust of highly toxic fluoride-beryllium pulp from reactor.
1 tbl, 1 ex
Title | Year | Author | Number |
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METHOD OF PRODUCTION OF AMMONIUM FLUORO-BERYLLATE | 2004 |
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RU2624749C2 |
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METHOD OF EXTRACTING BERYLLIUM BY ION EXCHANGE | 2014 |
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RU2571763C1 |
METHOD FOR LEACHING METALLIC COPPER | 2020 |
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RU2749961C1 |
REMOVAL OF NITROGEN FROM NITROGEN COMPOUNDS IN AQUEOUS PHASE | 1992 |
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RU2104951C1 |
UREA-CONTAINING ETCHING AGENT AND A METHOD FOR PREPARATION THEREOF | 2001 |
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RU2259422C2 |
Authors
Dates
2009-04-10—Published
2007-07-30—Filed