FIELD: chemistry.
SUBSTANCE: invention refers to method of isobutylene production by decomposition methyl-tertiary-butyl ether with heterogeneous catalyst at raised temperature and pressure, characterised that catalyst is multi-purpose synthetic zeolite NaX, while process is enables at atmospheric pressure with water vapour with observing the conditions as follows: temperature 200-250°C, volumetric MTBE feed rate 1.0-2.0 h-1. These conditions ensure minimal generation of MTBE decomposition by-products.
EFFECT: MTBE conversion per run is 96-99% with isobutylene selectivity at least 99%.
1 cl, 3 tbl, 9 ex
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Authors
Dates
2009-04-10—Published
2007-10-16—Filed