FIELD: chemistry.
SUBSTANCE: invention relates to rubber synthesis technology and can be used in the petrochemical industry. The method involves (co)polymerisation of olefin and/or diene hydrocarbons in a solution of paraffin and/or olefin type hydrocarbon solvent in the presence of a catalyst, deactivation of the catalyst and stabilisation of the polymer using an antioxidant in the presence or absence of methanol with a mixture of antioxidant, amine and/or phenol type or mixtures of their alkyl derivatives, - and synthetic fatty acid or C12-C20 fraction of synthetic fatty acids, introduced in a mixed hydrocarbon solvent, containing 0.05 to 40.0 wt % antioxidant, aromatic solvent and (co)polymerisation solvent. Synthetic fatty acid or C12-C20 fraction of synthetic fatty acids is added in amount ranging from 5 to 150 wt % monomer (co)polymerisation catalyst. Methanol is taken in amount of 0.25 to 1.50 mol/mol catalyst. Deactivation and stabilisation processes are carried out with intense stirring of the polymer solution and mixture of antioxidant, synthetic fatty acid or C12-C20 fraction of synthetic fatty acids, introduced in mixed hydrocarbon solvent in a non-volume mixer with rotational frequency of the stirring rod of 500-750 min-1. Deactivated and stabilised polymer solution is then kept for 0.5 to 1.0 h before washing and homogenisation.
EFFECT: use of the invention allows for reducing power consumption and improving quality of obtained rubber.
4 cl, 1 dwg, 9 ex, 4 tbl
Title | Year | Author | Number |
---|---|---|---|
SYNTHETIC RUBBER MANUFACTURE PROCESS | 2003 |
|
RU2261870C2 |
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RU2184123C1 |
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RU2148591C1 |
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RU2167165C1 |
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METHOD OF PREPARING ETHYLENE-PROPYLENE RUBBER | 2000 |
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RU2171818C1 |
METHOD OF ISOPRENE RUBBER PRODUCING | 1992 |
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RU2071964C1 |
METHOD OF STABILIZATION OF POLYMERS | 1999 |
|
RU2161631C1 |
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|
RU2288235C1 |
METHOD OF PRODUCTION OF POLYISOPRENE RUBBER | 2001 |
|
RU2190631C1 |
Authors
Dates
2009-11-10—Published
2008-06-03—Filed