FIELD: chemistry.
SUBSTANCE: invention relates to a method of purifying styrene from phenylacetylene impurities through hydrogenation with molecular hydrogen at high temperature in the presence of a gold-containing catalyst which contains gamma aluminium oxide. The method is characterised by that the catalyst is in form of gold metal particles with average size of 2-3 nm, and total content of gold in the catalyst is 0.01-0.03 wt %; the process is carried out in gaseous phase at temperature 140-160°C.
EFFECT: use of the method enables sharp reduction in consumption of precious metal in the catalyst while ensuring complete purification of styrene from phenylacetylene, prevention of loss of styrene and stable operation of the catalyst.
1 cl, 2 dwg, 2 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR SELECTIVE REMOVAL OF ACETYLENE HYDROCARBON ADMIXTURES FROM ETHYLENE MONOMERS AND METHOD TO THIS END | 2012 |
|
RU2501606C1 |
METHOD FOR PURIFICATION OF ETHYLENE FROM ADMIXTURES OF ACETYLENE | 2008 |
|
RU2383521C1 |
BIMETALLIC CATALYST FOR LIQUID-PHASE SELECTIVE HYDROGENATION OF ACETYLENIC HYDROCARBONS AND METHOD FOR ITS PRODUCTION | 2022 |
|
RU2786218C1 |
CATALYST FOR HYDROAMINATION OF LIQUID ACETYLENE HYDROCARBONS AND METHOD FOR HYDROAMINATION OF LIQUID ACETYLENE HYDROCARBONS USING SAID CATALYST | 2014 |
|
RU2566751C1 |
CATALYST FOR HYDROAMINATION OF ACETYLENE HYDROCARBONS AND METHOD FOR HYDROAMINATION OF ACETYLENE HYDROCARBONS USING SAID CATALYST | 2014 |
|
RU2544101C1 |
METHOD FOR PRODUCING PALLADIUM-CONTAINING CATALYST FOR HYDROGENATION OF ACETYLENE COMPOUNDS | 2022 |
|
RU2814116C1 |
REACTOR FOR LIQUID PHASE PURIFICATION OF STYRENE FRACTION FROM PHENYLACETILENE ADMIXTURE BY METHOD OF CATALYTIC SELECTIVE HYDRATION OF STYRENE FRACTION | 2012 |
|
RU2520461C1 |
CATALYST FOR SELECTIVE HYDROGENATION OF DIENE AND ACETYLENE HYDROCARBONS AND METHOD FOR PRODUCTION THEREOF | 2016 |
|
RU2669397C2 |
METHOD FOR SELECTIVE HYDROGENATION OF ACETYLENE HYDROCARBONS | 2015 |
|
RU2601751C1 |
METHOD OF SELECTIVE PHENYLACETYLENE HYDRATION IN PRESENCE OF STIROL | 2009 |
|
RU2505519C2 |
Authors
Dates
2010-04-10—Published
2008-07-21—Filed