FIELD: chemistry.
SUBSTANCE: invention relates to a method for synthesis of 2,3-benzo-5,7-disubstituted-1,4-cycloheptadiazines of general formula 
, where 1) R1=2-thienyl; R2=trifluoromethyl; 2) R1-R2=1,3-(5,5-dimethyl)cyclohexyl; 3) R1=R2=methyl, which can be used as extraction agents for non-ferrous and platinum-group metals, as well as in medicine. The method of involves reaction of ortho-phenylenediamine and the corresponding 1,3-diketone in molar ratio of components equal to 1:1 and while heating to temperature from 50°C to 80°C for 1-3 hours in dry benzol or without the benzol, and in the absence of a condensing agent.
EFFECT: wider field of use.
1 tbl, 3 ex
| Title |
Year |
Author |
Number |
| METHOD OF PRODUCING 2,2-DISUBSTITUTED-4,5-BENZO-CYCLOPENTADIIMINES-1,3 |
2010 |
- Bidman Tat'Jana Arkad'Evna
|
RU2430091C1 |
| LUMINESCENT ANIONIC COMPLEXES OF RARE-EARTH ELEMENTS WITH FLUORINATED PYRAZOLE-CONTAINING 1,3-DIKETONES AND METHOD FOR PRODUCTION THEREOF |
2011 |
- Tajdakov Il'Ja Viktorovich
- Vitukhnovskij Aleksej Grigor'Evich
- Lobanov Andrej Nikolaevich
|
RU2485162C1 |
| NEODYMIUM ARYL PHOSPHATES AND CATALYST FOR POLYMERISING CONJUGATED DIENES USING SAID NEODYMIUM ARYL PHOSPHATES |
2010 |
- Nifant'Ev Il'Ja Ehduardovich
- Tavtorkin Aleksandr Nikolaevich
- Gavrilenko Inna Fedorovna
- Glebova Natalija Nikolaevna
- Zolotarev Valentin Luk'Janovich
- Jakovlev Vladimir Aleksandrovich
|
RU2456292C2 |
| LUMINESCENT COMPLEXES OF RARE-EARTH ELEMENTS WITH PYRAZOLE-CONTAINING 1,3-DIKETONES AND METHOD OF PRODUCING SAID COMPOUNDS |
2011 |
- Tajdakov Il'Ja Viktorovich
- Vitukhnovskij Aleksej Grigor'Evich
- Lobanov Andrej Nikolaevich
|
RU2469041C1 |
| METHOD OF PREPARING 2-ALKYL- AND PHENYL-5,10-DIHYDROPHENAZINES |
1999 |
|
RU2171255C2 |
| METHOD OF PRODUCING MODIFIED RUBBER BY SOLUTION ANIONIC POLYMERISATION, A RUBBER COMPOSITION CONTAINING SUCH RUBBER AND USE THEREOF |
2016 |
- Averkov Aleksej Mikhajlovich
- Turenko Svetlana Viktorovna
- Kharlamova Ekaterina Vasilevna
|
RU2707102C1 |
| DIKETONE AS INTERMEDIATE FOR 3-HALOGENE-1H-PYRASOLES |
1996 |
- Zkhi Benksin
- Nevaz Murad
- Toli Dzhon Dzh.
- Bertensho Stefen
|
RU2251543C2 |
| LUMINESCENT COMPLEXES OF RARE-EARTH ELEMENTS WITH PYRAZOLE-CONTAINING FLUORINATED 1,3-DIKETONES AND METHOD FOR PRODUCTION THEREOF |
2011 |
- Tajdakov Il'Ja Viktorovich
- Vitukhnovskij Aleksej Grigor'Evich
- Lobanov Andrej Nikolaevich
- Krasnosel'Skij Sergej Sergeevich
|
RU2485163C1 |
| LUMINESCENT COMPLEXES OF RARE-EARTH ELEMENTS WITH PYRAZOLE-CONTAINING 1,3-DIKETONES AND METHOD FOR PRODUCTION THEREOF |
2011 |
- Tajdakov Il'Ja Viktorovich
- Vitukhnovskij Aleksej Grigor'Evich
- Lobanov Andrej Nikolaevich
|
RU2470026C1 |
| 4-SUBSTITUTED-3-(1-ALKYL-2-CHLORO-1H-INDOL-3-YL)FURAN-2,5-DIONES, SYNTHESIS METHOD THEREOF AND USE IN PHOTOCHEMICAL GENERATION OF STABLE FLUORESCENT COMPOUNDS AND 4,5-SUBSTITUTED-6-ALKYL-1H-FURO[3,4-c]CARBAZOLE-1,3(6H)-DIONES, SYNTHESIS METHOD THEREOF AND USE AS FLUOROPHORES |
2009 |
- Rybalkin Vladimir Petrovich
- Metelitsa Anatolij Viktorovich
- Levchenko Pavel Viktorovich
- Shepelenko Evgenij Nikolaevich
- Makarova Nadezhda Ivanovna
- Bren' Vladimir Aleksandrovich
- Minkin Vladimir Isaakovich
|
RU2396267C1 |
