FIELD: chemistry.
SUBSTANCE: present invention relates to a method for synthesis of 1-aminomethyl-2-phenylacetylenes of formula (1), 
where 
is characterised by that, phenylacetylene (Ph-C≡CH) is reacted with gem-diamines R2NCH2NR2, where R2N is as defined above, in the presence of a Sm(NO3)2*6H2O catalyst in molar ratio phenylacetylene: gem-diamine: Sm(NO3)2*6H2O=10:(8-12):(0.2-0.6) at 80°C and atmospheric pressure for 3-5 hours.
EFFECT: new method is designed for synthesis of 1-aminomethyl-2-phenylacetylenes, which can be used in fine organic synthesis, particularly for synthesis of scarce polycyclic compounds.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR SYNTHESIS OF ASYMMETRIC (-DI(AMINOMETHYL)ALKADIINES | 2009 |
|
RU2409544C2 |
| 1-AMINOMETHYL-α,ω-ALKADIINE SYNTHESIS METHOD | 2008 |
|
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| METHOD OF PRODUCING α,ω-DI(AMINOMETHYL)ALKADIINES | 2008 |
|
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|
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| METHOD OF PRODUCING SYMMETRICAL GEM-DIAMINES | 2008 |
|
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| METHOD OF PRODUCING N,N-DIMETHYL-3-PHENYL-2-PROPYNE-1-AMINE | 2007 |
|
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| 4-(DIMETHYLAMINO)-1-ALKYL-1-METHYL-2-ALKYN-1-OLS SYNTHESIS METHOD | 2008 |
|
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| METHOD FOR PREPARATION OF 1-(2-ALKYNYL)PIPERIDINES | 2008 |
|
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| METHOD OF PRODUCING 4-(DIMETHYLAMINO)-2-BUTINYL ALKANOATES | 2008 |
|
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| METHOD OF OBTAINING N,N,N,N-TETRASUBSTITUTED DI[4-(AMINOMETHYLSULFANYL)]PHENYL ETHERS | 2011 |
|
RU2466987C1 |
