FIELD: chemistry.
SUBSTANCE: invention relates to catalysts, specifically to a catalyst for synthesis of 1-(dimethylamino)-3-alkyl-2-propines. The invention describes a method for synthesis of 1-(dimethylamino)-3-alkyl-2-propines through aminomethylation of 1-alkynes using bisamine (N,N,N1,N1-tetramethylmethanediamine) in an argon atmosphere in the presence of a catalyst in form of 6-hydrous samaric nitrate Sm(NO3)2*6H2O.
EFFECT: said catalyst does not form explosive acetylides during aminomethylation of 1-alkynes in the presence of bisamine.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
4-(DIMETHYLAMINO)-1-ALKYL-1-METHYL-2-ALKYN-1-OLS SYNTHESIS METHOD | 2008 |
|
RU2378249C2 |
METHOD OF PRODUCING 4-(DIMETHYLAMINO)-2-BUTINYL ALKANOATES | 2008 |
|
RU2436766C2 |
METHOD OF PRODUCING N,N,N,N-TETRAMETHYL-2-BUTYNE-1,4-DIAMINE | 2010 |
|
RU2448951C2 |
METHOD OF PRODUCING N,N,N,N-TETRAMETHYL-2-BUTYNE-1,4-DIAMINE | 2008 |
|
RU2408572C2 |
METHOD FOR SYNTHESIS OF ASYMMETRIC (-DI(AMINOMETHYL)ALKADIINES | 2009 |
|
RU2409544C2 |
METHOD FOR SYNTHESIS OF 1-AMINOMETHYL-2-PHENYLACETYLENES | 2008 |
|
RU2391335C2 |
METHOD OF PRODUCING N,N-DIMETHYL-3-PHENYL-2-PROPYNE-1-AMINE | 2007 |
|
RU2349579C1 |
METHOD OF PRODUCING N,N,N,N-TETRAMETHYLALKADIYNEDIAMINES | 2007 |
|
RU2373189C2 |
METHOD OF PRODUCING 2-[(DIMETHYLAMINO)METHYL]PHENOL | 2008 |
|
RU2384567C2 |
METHOD OF PRODUCING N,N,N,N-TETRAMETHYL-2-BUTENE-1,4-DIAMINE | 2008 |
|
RU2440329C2 |
Authors
Dates
2010-09-20—Published
2008-09-02—Filed