FIELD: chemistry.
SUBSTANCE: invention relates to a method for producing polymeric petroleum resins. The invention describes a method of producing polymeric petroleum resins which involves polymerisation of unsaturated compounds of the fraction of liquid products of pyrolysis of straight-run petrol with boiling range of 130-190°C in the presence of catalyst systems: titanium tetrachloride and an organoaluminium compound in molar ratio: TiCL4 : Al(C2H5)2Cl = 1:(0.1-3.0); TiCl4 : Al(C2H5)3 = 1:(0.1-3.0); TiCl4 : Al(iso-C4H9)3 = 1:(0.1-3.0).The method is distinguished by that the catalyst is deactivated with triglycidyl ethers of polyoxypropylenetriols manufactured under the trademark Laproxide 603 and Laproxide 703, having general formula:
, where a, b, c = 1-3, with molecular weight of 434-782, and taken in molar ratio to the catalyst system of 1.0:2.1.The deactivation products remain in the composition of the polymeric petroleum resins.
EFFECT: simple technology of producing polymeric petroleum resins, improved environmental safety of the process, improved sanitary and hygienic conditions during production.
1 cl, 3 tbl, 3 ex
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|
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METHOD OF PRODUCING POLYMERIC PETROLEUM RESINS | 2011 |
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RU2451694C1 |
METHOD FOR PRODUCTION OF OIL-RESIN FILM-FORMING AGENT | 2004 |
|
RU2261872C1 |
Authors
Dates
2010-07-27—Published
2008-12-22—Filed