FIELD: chemistry.
SUBSTANCE: invention relates to a method of removing radioactive contaminants. The method of deactivating and cleaning a solid organic substrate contaminated with solid radioactive dispersed inorganic contaminants, in which the substrate is brought into contact with a water-free extraction medium, containing: densely compressed CO2; non-halogenated surfactant selected from block-copolymers of polyethylene oxide PEO and polypropylene oxide PPO, such as double-block copolymers (EO)x-(PO)y, tri-block copolymers (EO)x-(PO)y-(EO)x and tri-block copolymers (PO)x-(EO)y-(PO)x, where x and y are integers from 2 to 80, where x is not equal to y, and polydi(from 1 to 6 C)alkylsiloxane, such as polydimethylsiloxane (PDMS); a complexing agent selected from tributylphosphate (TBP), crown ethers, tributylphosphine oxide, triphenylphosphine oxide; and tri(n-octyl)phosphine oxide; and a substrate and/or extraction medium are subjected to mechanical action simultaneously with the contact operation.
EFFECT: invention provides satisfactory deactivation of substrates and prevents repeated contamination.
28 cl, 5 dwg, 4 tbl, 7 ex
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Authors
Dates
2011-07-10—Published
2007-02-23—Filed