FIELD: oil and gas industry.
SUBSTANCE: invention refers to method for obtaining high-octane benzene and/or aromatic hydrocarbons with low benzene content from hydrocarbon raw material, namely aliphatic hydrocarbons C5-C12 or aliphatic oxygen-containing compounds C1-C12, including in composition of basic products and by-products in oil, gas, chemical industry; phase of raw material contact in the first reaction zone is conducted at temperature of 400-600°C, pressure of 0.1-4.0 MPa and mass raw material supply rate of 1 -200 h-1 with aromatisation catalyst on the basis of modified zeolite of MFI structural type which is characterised with value of molar ratio SiO2/Al2O3 20-133, residual content of sodium ions of less than 0.1 %, which is treated in addition with 0.01-2.0 "н" solution of ammonium fluoride. Obtained reaction flow is subject to contact in the second reaction zone at temperature of 300-400°C, pressure of 0.1-4.0 MPa and mass raw material supply rate of 1-40 h-1 with catalyst of alkylation and/or transalkylation; at that, flow temperature at the inlet to the second reaction zone is not less than by 70°C lower than flow temperature at the inlet to the first reaction zone.
EFFECT: higher capacity of the process and output of gasoline.
7 cl, 24 ex, 3 tbl
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR CONVERTING ALIPHATIC C-C HYDROCARBONS AND/OR ALIPHATIC OXYGEN-CONTAINING C-C COMPOUNDS, METHOD OF PRODUCING SAID CATALYST AND METHOD OF PRODUCING HIGH-OCTANE PETROL OR AROMATIC HYDROCARBONS | 2008 |
|
RU2372988C1 |
PROCEDURE FOR PRODUCTION OF HIGH-OCTANE BENZINE OR AROMATIC HYDROCARBONS | 2009 |
|
RU2417249C1 |
ZEOLITE-BEARING CATALYST, METHOD OF ITS PRODUCTION AND METHOD OF CONVERTING LOW-OCTANE GASOLINE IN HIGH-OCTANE GASOLINE WITH AND WITHOUT HYDROGEN | 2011 |
|
RU2480282C2 |
CATALYST AND METHOD FOR AROMATISATION OF C-C GASES, LIGHT HYDROCARBON FRACTIONS OF ALIPHATIC ALCOHOLS, AS WELL AS MIXTURES THEREOF | 2014 |
|
RU2544017C1 |
METHOD FOR PRODUCTION OF HIGH-ANTIKNOCK GASOLINE FRACTIONS AND AROMATIC HYDROCARBONS (OPTIONS) | 2001 |
|
RU2208624C2 |
OBTAINING A ZSM-5 BASED CATALYST; USE IN PROCESS OF ETHYLBENZENE DEALKYLATION | 2017 |
|
RU2741547C2 |
CATALYST FOR AROMATIZATION OF C-C-HYDROCARBONS | 1990 |
|
SU1714836A1 |
CATALYST AND A METHOD FOR PRODUCTION OF HIGH-OCTANE FUELS AND PROPANE-BUTANE FRACTION USING THIS CATALYST | 2003 |
|
RU2243820C1 |
METHOD OF HEAVY AROMATIC HYDROCARBON PROCESSING | 1998 |
|
RU2183611C2 |
ZEOLITE-CONTAINING CATALYST AND METHOD OF CONVERTING $$$-HYDROCARBONS INTO HIGH-ANTIKNOCK GASOLINE COMPONENT OR AROMATIC HYDROCARBON CONCENTRATE | 1996 |
|
RU2100075C1 |
Authors
Dates
2011-07-27—Published
2009-11-05—Filed