FIELD: chemistry.
SUBSTANCE: invention relates to use of terpolymers of propylene/butylene/ethylene with a nucleating agent to form sterilising films obtained via extrusion blowing. A film is obtained from a polymer composition containing (i) and (ii) 0.001-1.0 wt % of one or more phosphorus-containing and/or polymeric α-nucleating agents. The terpolymer of propylene, ethylene and butylene consists of 86.0-98.0 wt % propylene, 2.0-12.0 wt % butylene and 0.1 to less than 1.0 wt % ethylene. The obtained films have a) turbidity according to ASTM D 1003-92 for a 50 mcm film less than 8% before and after steam sterilisation at 121°C for 30 minutes and b) lustre at 20° according to DIN 67530 for a 50 mcm film of at least 55% before steam sterilisation at 121°C for 30 minutes and at least 60% after steam sterilisation at 121°C for 30 minutes. The films are sterilisable and have excellent optical and mechanical properties.
EFFECT: improved method of obtaining films.
16 cl, 4 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
POLYPROPYLENE COMPOSITION | 2019 |
|
RU2758954C1 |
METHOD OF PRODUCING PROPYLENE TERPOLYMERS | 2008 |
|
RU2458734C2 |
POLYPROPYLENE FILMS WITH IMPROVED OPTICAL AND MECHANICAL PROPERTIES | 2015 |
|
RU2705056C2 |
SOLID ALKYLARYLPHOSPHITE COMPOSITIONS AND METHODS OF OBTAINING THEREOF | 2010 |
|
RU2541543C2 |
POLYPROPYLENE-BASED FILM | 2021 |
|
RU2815096C1 |
MULTILAYER FILM WITH IMPROVED PROPERTIES | 2021 |
|
RU2805350C1 |
SYNTHETIC POLYMERS CONTAINING MIXTURES AS ADDITIONS OF ENHANCED ACTION | 2000 |
|
RU2251562C2 |
METHOD OF NUCLEATING POLYPROPYLENE RESINS | 2006 |
|
RU2413742C2 |
FIRE-RETARDANT POLYOLEFIN COMPOUNDS | 2016 |
|
RU2718926C2 |
NEW NUCLEATED PROPYLENE-ETHYLENE-BUTYLENE TERPOLYMERS AND CAST ARTICLES MADE THEREFROM | 2017 |
|
RU2701732C1 |
Authors
Dates
2011-09-10—Published
2008-07-14—Filed