FIELD: chemistry.
SUBSTANCE: method of producing polycarbonate resin involves a reesterification reaction between an aromatic dihydroxy compound and diphenyl carbonate and/or substituted diphenyl carbonate. The molar ratio of diphenyl carbonate and/or substituted diphenyl carbonate to the aromatic dihydroxy compound ranges from 1.01 to 1.30. The aromatic polycarbonate resin is continuously produced with viscosity-average molecular weight from 10000 to 20000 for a certain period of time. When the reaction stops, the reactor is washed with a molten mixture of an aromatic dihydroxy compound with diphenyl carbonate and/or substituted diphenyl carbonate. The reactor is then washed with an aromatic monohydroxy compound.
EFFECT: providing a method of producing a polycarbonate resin, having a less intense colour and containing a low amount of undesirable crystalline impurities and such undesirable impurities as gel.
2 cl, 1 tbl, 1 dwg, 2 ex
Title | Year | Author | Number |
---|---|---|---|
CONTINUOUS METHOD AND APPARATUS FOR PRODUCING AROMATIC POLYCARBONATE | 2007 |
|
RU2413739C2 |
METHOD OF PRODUCING AROMATIC POLYCARBONATE | 2007 |
|
RU2380382C2 |
POLYCARBONATE RESINS AND METHODS OF PRODUCING SAID RESINS | 2008 |
|
RU2418819C2 |
METHOD OF PRODUCING POLYCARBONATE RESIN | 2007 |
|
RU2407757C2 |
METHOD FOR CONTINUOUS PRODUCTION OF HIGH-MOLECULAR WEIGHT POLYCARBONATE RESIN | 2013 |
|
RU2630678C2 |
POLYCARBONATE RESIN COMPOSITION FOR USE IN PRODUCTION OF SUBSTRATE FOR OPTICAL INFORMATION CARRIER | 2004 |
|
RU2297430C2 |
METHOD AND DEVICE FOR PRODUCING POLYCARBONATE | 2013 |
|
RU2622641C2 |
POLYCARBONATE COPOLYMER POSSESSING HIGH FLOW CHARACTERISTICS, METHOD FOR PRODUCING AROMATIC POLYCARBONATE RESIN HAVING HIGH MOLECULAR WEIGHT AND AROMATIC POLYCARBONATE COMPOUND | 2012 |
|
RU2569850C2 |
POLYCARBONATES WITH IMPROVED CHARACTERISTIC OF FLUIDITY, WHICH CONTAIN CYCLIC OLIGOMERS | 2009 |
|
RU2491305C9 |
IMPROVED FLUIDITY POLYCARBONATES CONTAINING REGROUPED STRUCTURES, CYCLIC AND LINEAR OLIGOMERS | 2009 |
|
RU2496801C9 |
Authors
Dates
2011-10-10—Published
2007-09-25—Filed