METHOD OF PREPARING AQUEOUS DISPERSIONS OF TiO IN FORM OF NANOPARTICLES AND DISPERSIONS OBTAINED USING SAID METHOD Russian patent published in 2011 - IPC C01G23/53 B82B1/00 

Abstract RU 2431604 C2

FIELD: chemistry.

SUBSTANCE: method of preparing aqueous dispersions of TiO2 nanoparticles in form of anatase involves reaction of titanium alkoxide with water in the presence of a mineral acid and a nonionic surfactant while heating. The titanium alkoxide is selected from a group comprising titanium methoxide, ethoxide, n-propoxide, isopropoxide, n-butoxide and isobutoxide. The mineral acid is a halogen acid. The surfactants have a polar functional group of the ether or ester type. The titanium alkoxide/halogen acid molar ratio ranges from 0.005 to 15. In an alternative method, the solution which contains titanium alkoxide, mineral acid and surfactant is mixed with a transition metal salt, for example Ag or Cu or Ce, and a dispersion of TiO2 nanoparticles is obtained, where Ti is deposited on the said metal. The obtained dispersions of TiO2 nanoparticles are used to produce photocatalytic coatings on a surface which requires such processing, as well as for photocatalytic cleaning of gases and liquids.

EFFECT: method enables to obtain a dispersion of TiO2 nanoparticles which do not exhibit adhesion, coagulation and deposition of a solid material even after prolonged storage of the dispersed product, and are uniform, have photocatalytic activity and are transparent.

18 cl, 1 dwg, 7 ex

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RU 2 431 604 C2

Authors

Baldi Dzhovanni

Bitossi Marko

Bartsanti Andrea

Dates

2011-10-20Published

2007-01-29Filed