MATERIAL WITH COMPOSITE PARTICLES ON SUBSTRATE, METHOD OF PRODUCING SAID MATERIAL AND METHOD OF PRODUCING COMPOUNDS USING MATERIAL WITH COMPOSITE PARTICLES ON SUBSTRATE AS CHEMICAL SYNTHESIS CATALYST Russian patent published in 2011 - IPC B01J23/89 B01J21/00 B01J37/04 B01J37/08 C07C69/54 B82B3/00 

FIELD: chemistry.

SUBSTANCE: invention relates to materials with composite particles on a substrate. Described is material with composite particles on a substrate, containing: composite particles, which are formed from oxidised nickel and X, where X denotes at least one of elements selected from a group consisting of palladium, platinum, ruthenium, gold, silver and copper; and a substrate on which composite particles are deposited, where the material with composite particles on a substrate has a layer on which composite particles are localised. Described is a method of producing said material, in which composite particles formed from oxidised nickel and X, where X is an element given above, are deposited on a substrate, comprising: a first step where a mixture is obtained at temperature of at least 60°C by mixing an aqueous suspension, having a substrate on which an oxide of at least one basic metal is deposited, said metal selected from a group consisting of alkali metal, alkali-earth metals and rare-earth metals, and acidic aqueous solution of a soluble metal salt containing nickel and X, and a second step for thermal treatment of a precursor contained in said mixture. Described is a method of producing a carboxylic ester, where: an aldehyde and an alcohol react in the presence of oxygen using material containing the described composite particles on a substrate as a catalyst.

EFFECT: obtaining material with composite particles on a substrate, which has catalytic activity in carboxylic ester synthesis reactions.

16 cl, 1 tbl, 4 dwg, 11 ex